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Discussion of precise voltage measurement

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low emf solder

JL
Juris L
Fri, Oct 28, 2016 8:42 AM

Found reference to optimal emf solder composition cadmium/tin alloy
(70 %/30 %) in JJ array measurement article page 12.

www.bipm.org/utils/common/pdf/rapportBIPM/2011/05.pdf

Quick look at ebay show 1/4 kg of pure cadmium cost 10$ (item 111333082639),
so you can make quite a lot of solder for cheap ...

Also interesting way to thermally anchor interconnection leads to
copper block in page 11.

J.

Found reference to optimal emf solder composition cadmium/tin alloy (70 %/30 %) in JJ array measurement article page 12. www.bipm.org/utils/common/pdf/rapportBIPM/2011/05.pdf Quick look at ebay show 1/4 kg of pure cadmium cost 10$ (item 111333082639), so you can make quite a lot of solder for cheap ... Also interesting way to thermally anchor interconnection leads to copper block in page 11. J.
EB
ed breya
Fri, Oct 28, 2016 4:39 PM

I would recommend against trying to use cadmium - it's very toxic, which
is why Cd-based solders are rare nowadays. They are probably still made,
but for lab or industrial use with proper handling. If you try to alloy
it with Sn yourself without proper handling, you could get poisoned. You
can't just throw the ingredients in a solder pot and expect good results.

Ed

I would recommend against trying to use cadmium - it's very toxic, which is why Cd-based solders are rare nowadays. They are probably still made, but for lab or industrial use with proper handling. If you try to alloy it with Sn yourself without proper handling, you could get poisoned. You can't just throw the ingredients in a solder pot and expect good results. Ed
N
NeonJohn
Fri, Oct 28, 2016 9:09 PM

Let's don't get carried away with cadmium toxicity.  Yes, it is toxic is
sufficient dose but the LD50 dose for Cd is  750 mg/kg while the value
for lead is around 450mg/kg.

As far as dumping it in a solder pot, that works just fine for me.  It's
cheaper to buy 50/50 plumber's bar solder and then add the appropriate
amount of lead to get to the eutectic point.

One should also realize that cad-plated hardware is still available.  I
get mine from McMaster-Carr.

John

On 10/28/2016 12:39 PM, ed breya wrote:

I would recommend against trying to use cadmium - it's very toxic, which
is why Cd-based solders are rare nowadays. They are probably still made,
but for lab or industrial use with proper handling. If you try to alloy
it with Sn yourself without proper handling, you could get poisoned. You
can't just throw the ingredients in a solder pot and expect good results.

Ed


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--
John DeArmond
Tellico Plains, Occupied TN
http://www.tnduction.com    <-- THE source for induction heaters
http://www.neon-john.com    <-- email from here
http://www.johndearmond.com <-- Best damned Blog on the net
PGP key: wwwkeys.pgp.net: BCB68D77

Let's don't get carried away with cadmium toxicity. Yes, it is toxic is sufficient dose but the LD50 dose for Cd is 750 mg/kg while the value for lead is around 450mg/kg. As far as dumping it in a solder pot, that works just fine for me. It's cheaper to buy 50/50 plumber's bar solder and then add the appropriate amount of lead to get to the eutectic point. One should also realize that cad-plated hardware is still available. I get mine from McMaster-Carr. John On 10/28/2016 12:39 PM, ed breya wrote: > I would recommend against trying to use cadmium - it's very toxic, which > is why Cd-based solders are rare nowadays. They are probably still made, > but for lab or industrial use with proper handling. If you try to alloy > it with Sn yourself without proper handling, you could get poisoned. You > can't just throw the ingredients in a solder pot and expect good results. > > Ed > _______________________________________________ > volt-nuts mailing list -- volt-nuts@febo.com > To unsubscribe, go to > https://www.febo.com/cgi-bin/mailman/listinfo/volt-nuts > and follow the instructions there. > -- John DeArmond Tellico Plains, Occupied TN http://www.tnduction.com <-- THE source for induction heaters http://www.neon-john.com <-- email from here http://www.johndearmond.com <-- Best damned Blog on the net PGP key: wwwkeys.pgp.net: BCB68D77
NM
Neville Michie
Fri, Oct 28, 2016 9:33 PM

LD50 is not the only consideration. From Wikipedia:

"The International Agency for Research on Cancer has classified cadmium and cadmium compounds as carcinogenic to humans."

FWIW

Neville Michie

On 29 Oct 2016, at 8:09 AM, NeonJohn jgd@neon-john.com wrote:

Let's don't get carried away with cadmium toxicity.  Yes, it is toxic is
sufficient dose but the LD50 dose for Cd is  750 mg/kg while the value
for lead is around 450mg/kg.

As far as dumping it in a solder pot, that works just fine for me.  It's
cheaper to buy 50/50 plumber's bar solder and then add the appropriate
amount of lead to get to the eutectic point.

One should also realize that cad-plated hardware is still available.  I
get mine from McMaster-Carr.

John

On 10/28/2016 12:39 PM, ed breya wrote:

I would recommend against trying to use cadmium - it's very toxic, which
is why Cd-based solders are rare nowadays. They are probably still made,
but for lab or industrial use with proper handling. If you try to alloy
it with Sn yourself without proper handling, you could get poisoned. You
can't just throw the ingredients in a solder pot and expect good results.

Ed


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--
John DeArmond
Tellico Plains, Occupied TN
http://www.tnduction.com    <-- THE source for induction heaters
http://www.neon-john.com    <-- email from here
http://www.johndearmond.com <-- Best damned Blog on the net
PGP key: wwwkeys.pgp.net: BCB68D77


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LD50 is not the only consideration. From Wikipedia: "The International Agency for Research on Cancer has classified cadmium and cadmium compounds as carcinogenic to humans." FWIW Neville Michie > On 29 Oct 2016, at 8:09 AM, NeonJohn <jgd@neon-john.com> wrote: > > Let's don't get carried away with cadmium toxicity. Yes, it is toxic is > sufficient dose but the LD50 dose for Cd is 750 mg/kg while the value > for lead is around 450mg/kg. > > As far as dumping it in a solder pot, that works just fine for me. It's > cheaper to buy 50/50 plumber's bar solder and then add the appropriate > amount of lead to get to the eutectic point. > > One should also realize that cad-plated hardware is still available. I > get mine from McMaster-Carr. > > John > > > On 10/28/2016 12:39 PM, ed breya wrote: >> I would recommend against trying to use cadmium - it's very toxic, which >> is why Cd-based solders are rare nowadays. They are probably still made, >> but for lab or industrial use with proper handling. If you try to alloy >> it with Sn yourself without proper handling, you could get poisoned. You >> can't just throw the ingredients in a solder pot and expect good results. >> >> Ed >> _______________________________________________ >> volt-nuts mailing list -- volt-nuts@febo.com >> To unsubscribe, go to >> https://www.febo.com/cgi-bin/mailman/listinfo/volt-nuts >> and follow the instructions there. >> > > -- > John DeArmond > Tellico Plains, Occupied TN > http://www.tnduction.com <-- THE source for induction heaters > http://www.neon-john.com <-- email from here > http://www.johndearmond.com <-- Best damned Blog on the net > PGP key: wwwkeys.pgp.net: BCB68D77 > _______________________________________________ > volt-nuts mailing list -- volt-nuts@febo.com > To unsubscribe, go to https://www.febo.com/cgi-bin/mailman/listinfo/volt-nuts > and follow the instructions there.
PK
Poul-Henning Kamp
Fri, Oct 28, 2016 10:40 PM

Let's don't get carried away with cadmium toxicity.  Yes, it is toxic is
sufficient dose but the LD50 dose for Cd is  750 mg/kg while the value
for lead is around 450mg/kg.

Read how a professional chemist describes cadmium:

http://blogs.sciencemag.org/pipeline/archives/2013/05/08/things_i_wont_work_with_dimethylcadmium

--
Poul-Henning Kamp      | UNIX since Zilog Zeus 3.20
phk@FreeBSD.ORG        | TCP/IP since RFC 956
FreeBSD committer      | BSD since 4.3-tahoe
Never attribute to malice what can adequately be explained by incompetence.

-------- In message <c4a50a25-5082-c8ba-b225-fce103a5c774@neon-john.com>, NeonJohn writes: >Let's don't get carried away with cadmium toxicity. Yes, it is toxic is >sufficient dose but the LD50 dose for Cd is 750 mg/kg while the value >for lead is around 450mg/kg. Read how a professional chemist describes cadmium: http://blogs.sciencemag.org/pipeline/archives/2013/05/08/things_i_wont_work_with_dimethylcadmium -- Poul-Henning Kamp | UNIX since Zilog Zeus 3.20 phk@FreeBSD.ORG | TCP/IP since RFC 956 FreeBSD committer | BSD since 4.3-tahoe Never attribute to malice what can adequately be explained by incompetence.
DD
Dr. David Kirkby (Kirkby Microwave Ltd)
Sat, Oct 29, 2016 12:39 AM

On 28 Oct 2016 15:25, "Juris L" juris.l@gmail.com wrote:

Found reference to optimal emf solder composition cadmium/tin alloy
(70 %/30 %) in JJ array measurement article page 12.

I wonder how practical it is to weld test leads, so there's no solder or
thermal EMF.

I know that this will sound crazy, and probably is, but could one weld
components to a PCB?

I don't even have the excuse of been drunk or taking drugs,  but I will
risk ridicule for making the above comment!  Sometimes thinking out of the
box is useful.

Dave.

On 28 Oct 2016 15:25, "Juris L" <juris.l@gmail.com> wrote: > > Found reference to optimal emf solder composition cadmium/tin alloy > (70 %/30 %) in JJ array measurement article page 12. I wonder how practical it is to weld test leads, so there's no solder or thermal EMF. I know that this will sound crazy, and probably is, but could one weld components to a PCB? I don't even have the excuse of been drunk or taking drugs, but I will risk ridicule for making the above comment! Sometimes thinking out of the box is useful. Dave.
BG
Bruce Griffiths
Sat, Oct 29, 2016 12:42 AM

Laser welding should work for either similar or dissimilar materials.At one time microwire PCBs  used stainless steel  wires were welded to stainless lands.
Bruce 

On Saturday, 29 October 2016 1:39 PM, Dr. David Kirkby (Kirkby Microwave Ltd) <drkirkby@kirkbymicrowave.co.uk> wrote:

On 28 Oct 2016 15:25, "Juris L" juris.l@gmail.com wrote:

Found reference to optimal emf solder composition cadmium/tin alloy
(70 %/30 %) in JJ array measurement article page 12.

I wonder how practical it is to weld test leads, so there's no solder or
thermal EMF.

I know that this will sound crazy, and probably is, but could one weld
components to a PCB?

I don't even have the excuse of been drunk or taking drugs,  but I will
risk ridicule for making the above comment!  Sometimes thinking out of the
box is useful.

Dave.


volt-nuts mailing list -- volt-nuts@febo.com
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Laser welding should work for either similar or dissimilar materials.At one time microwire PCBs  used stainless steel  wires were welded to stainless lands. Bruce  On Saturday, 29 October 2016 1:39 PM, Dr. David Kirkby (Kirkby Microwave Ltd) <drkirkby@kirkbymicrowave.co.uk> wrote: On 28 Oct 2016 15:25, "Juris L" <juris.l@gmail.com> wrote: > > Found reference to optimal emf solder composition cadmium/tin alloy > (70 %/30 %) in JJ array measurement article page 12. I wonder how practical it is to weld test leads, so there's no solder or thermal EMF. I know that this will sound crazy, and probably is, but could one weld components to a PCB? I don't even have the excuse of been drunk or taking drugs,  but I will risk ridicule for making the above comment!  Sometimes thinking out of the box is useful. Dave. _______________________________________________ volt-nuts mailing list -- volt-nuts@febo.com To unsubscribe, go to https://www.febo.com/cgi-bin/mailman/listinfo/volt-nuts and follow the instructions there.
HD
Howard Davidson
Sat, Oct 29, 2016 12:46 AM

I note that  I weld thermocouples.
 hld

Howard L. Davidson
hld42@att.net

  From: Dr. David Kirkby (Kirkby Microwave Ltd) <drkirkby@kirkbymicrowave.co.uk>

To: Discussion of precise voltage measurement volt-nuts@febo.com
Sent: Friday, October 28, 2016 5:39 PM
Subject: Re: [volt-nuts] low emf solder

On 28 Oct 2016 15:25, "Juris L" juris.l@gmail.com wrote:

Found reference to optimal emf solder composition cadmium/tin alloy
(70 %/30 %) in JJ array measurement article page 12.

I wonder how practical it is to weld test leads, so there's no solder or
thermal EMF.

I know that this will sound crazy, and probably is, but could one weld
components to a PCB?

I don't even have the excuse of been drunk or taking drugs,  but I will
risk ridicule for making the above comment!  Sometimes thinking out of the
box is useful.

Dave.


volt-nuts mailing list -- volt-nuts@febo.com
To unsubscribe, go to https://www.febo.com/cgi-bin/mailman/listinfo/volt-nuts
and follow the instructions there.

I note that  I weld thermocouples.  hld Howard L. Davidson hld42@att.net From: Dr. David Kirkby (Kirkby Microwave Ltd) <drkirkby@kirkbymicrowave.co.uk> To: Discussion of precise voltage measurement <volt-nuts@febo.com> Sent: Friday, October 28, 2016 5:39 PM Subject: Re: [volt-nuts] low emf solder On 28 Oct 2016 15:25, "Juris L" <juris.l@gmail.com> wrote: > > Found reference to optimal emf solder composition cadmium/tin alloy > (70 %/30 %) in JJ array measurement article page 12. I wonder how practical it is to weld test leads, so there's no solder or thermal EMF. I know that this will sound crazy, and probably is, but could one weld components to a PCB? I don't even have the excuse of been drunk or taking drugs,  but I will risk ridicule for making the above comment!  Sometimes thinking out of the box is useful. Dave. _______________________________________________ volt-nuts mailing list -- volt-nuts@febo.com To unsubscribe, go to https://www.febo.com/cgi-bin/mailman/listinfo/volt-nuts and follow the instructions there.
SS
Scott Stobbe
Sat, Oct 29, 2016 1:04 AM

"chip on board", not sure that it wouldnt help

On Friday, 28 October 2016, Dr. David Kirkby (Kirkby Microwave Ltd) <
drkirkby@kirkbymicrowave.co.uk> wrote:

On 28 Oct 2016 15:25, "Juris L" <juris.l@gmail.com javascript:;> wrote:

Found reference to optimal emf solder composition cadmium/tin alloy
(70 %/30 %) in JJ array measurement article page 12.

I wonder how practical it is to weld test leads, so there's no solder or
thermal EMF.

I know that this will sound crazy, and probably is, but could one weld
components to a PCB?

I don't even have the excuse of been drunk or taking drugs,  but I will
risk ridicule for making the above comment!  Sometimes thinking out of the
box is useful.

Dave.


volt-nuts mailing list -- volt-nuts@febo.com javascript:;
To unsubscribe, go to https://www.febo.com/cgi-bin/
mailman/listinfo/volt-nuts
and follow the instructions there.

"chip on board", not sure that it wouldnt help On Friday, 28 October 2016, Dr. David Kirkby (Kirkby Microwave Ltd) < drkirkby@kirkbymicrowave.co.uk> wrote: > On 28 Oct 2016 15:25, "Juris L" <juris.l@gmail.com <javascript:;>> wrote: > > > > Found reference to optimal emf solder composition cadmium/tin alloy > > (70 %/30 %) in JJ array measurement article page 12. > > I wonder how practical it is to weld test leads, so there's no solder or > thermal EMF. > > I know that this will sound crazy, and probably is, but could one weld > components to a PCB? > > I don't even have the excuse of been drunk or taking drugs, but I will > risk ridicule for making the above comment! Sometimes thinking out of the > box is useful. > > Dave. > _______________________________________________ > volt-nuts mailing list -- volt-nuts@febo.com <javascript:;> > To unsubscribe, go to https://www.febo.com/cgi-bin/ > mailman/listinfo/volt-nuts > and follow the instructions there. >
SS
Scott Stobbe
Sat, Oct 29, 2016 1:18 AM

Typing on phone... If the bond wires are gold they still are dissimilar to
pcb copper, but if they were copper bond wires, thermal gradients would be
less of an issue.

On Friday, 28 October 2016, Scott Stobbe scott.j.stobbe@gmail.com wrote:

"chip on board", not sure that it wouldnt help

On Friday, 28 October 2016, Dr. David Kirkby (Kirkby Microwave Ltd) <
drkirkby@kirkbymicrowave.co.uk
javascript:_e(%7B%7D,'cvml','drkirkby@kirkbymicrowave.co.uk');> wrote:

On 28 Oct 2016 15:25, "Juris L" juris.l@gmail.com wrote:

Found reference to optimal emf solder composition cadmium/tin alloy
(70 %/30 %) in JJ array measurement article page 12.

I wonder how practical it is to weld test leads, so there's no solder or
thermal EMF.

I know that this will sound crazy, and probably is, but could one weld
components to a PCB?

I don't even have the excuse of been drunk or taking drugs,  but I will
risk ridicule for making the above comment!  Sometimes thinking out of the
box is useful.

Dave.


volt-nuts mailing list -- volt-nuts@febo.com
To unsubscribe, go to https://www.febo.com/cgi-bin/m
ailman/listinfo/volt-nuts
and follow the instructions there.

Typing on phone... If the bond wires are gold they still are dissimilar to pcb copper, but if they were copper bond wires, thermal gradients would be less of an issue. On Friday, 28 October 2016, Scott Stobbe <scott.j.stobbe@gmail.com> wrote: > "chip on board", not sure that it wouldnt help > > On Friday, 28 October 2016, Dr. David Kirkby (Kirkby Microwave Ltd) < > drkirkby@kirkbymicrowave.co.uk > <javascript:_e(%7B%7D,'cvml','drkirkby@kirkbymicrowave.co.uk');>> wrote: > >> On 28 Oct 2016 15:25, "Juris L" <juris.l@gmail.com> wrote: >> > >> > Found reference to optimal emf solder composition cadmium/tin alloy >> > (70 %/30 %) in JJ array measurement article page 12. >> >> I wonder how practical it is to weld test leads, so there's no solder or >> thermal EMF. >> >> I know that this will sound crazy, and probably is, but could one weld >> components to a PCB? >> >> I don't even have the excuse of been drunk or taking drugs, but I will >> risk ridicule for making the above comment! Sometimes thinking out of the >> box is useful. >> >> Dave. >> _______________________________________________ >> volt-nuts mailing list -- volt-nuts@febo.com >> To unsubscribe, go to https://www.febo.com/cgi-bin/m >> ailman/listinfo/volt-nuts >> and follow the instructions there. >> >